Perovskite Hydroxide CoSn(OH)<sub>6</sub> Nanocubes\nfor Efficient Photoreduction of CO<sub>2</sub> to CO
Yan Gao (93649)Lu Ye (1978777)Shuyan Cao (4236961)Hu Chen (19500)Yanan Yao (115727)Jian Jiang (566504)Licheng Sun (1306302)
Abstract
Perovskite\nhydroxide CoSn(OH)<sub>6</sub> nanoparticles were synthesized\nand used for the first time in the photocatalytic reduction of CO<sub>2</sub> to CO. Under mild reaction conditions and using [Ru(bpy)<sub>3</sub>](PF<sub>6</sub>)<sub>2</sub> as the photosensitizer, a high\nphotocatalytic efficiency of 19.3 μmol for CO evolution with\na high selectivity of 86.46% was obtained. The photocatalytic activity\nand CO selectivity were further improved by adding weak Brönsted\nacids, as proton sources, to the system.
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