新しい合成試剤の開発研究-官能化α,β-不飽和ケトンを用いる合成反応

Abstract

Presented are reactivities of 2-oxo-alkenylphosphonates as hetero 1,3-diene and some synthetic utilization of these new types of functionalized α, β-unsaturated ketones via hetero Diels-Alder reaction or Michael reaction. Asymmetric hetero Diels-Alder reactions of sulfur functionalized α, β-unsaturated ketones are also presented.