CaSrxCu3−xTi4O12 Ceramic Oxide Modified with Graphene Oxide and Reduced Graphene Oxide for Supercapacitor Applications

Abstract

This study investigates CaCu3−xSrxTi4O12 (CCSTO) systems synthesized using the solid-state method, with x compositions of 0.00, 0.15, and 3.00. The samples were modified using 6 wt% graphene oxide (GO) and reduced GO (rGO) prepared via Hummer’s method to evaluate their performance as electrodes in supercapacitors. The results indicate that the addition of 6wt% rGO to CCTO (CCTO-6rGO) led to an improvement in specific capacitance, reaching 237.76 mF·g−1 at a scan rate of 10 mV/s, compared to 29.86 mF·g−1 for pure CCTO and only 7.83 mF·g−1 for CCTO-6GO, suggesting that rGO enhances charge storage. For the CCTO15Sr samples, CCTO15Sr-6rGO exhibited the highest specific capacitance, with 321.63 mF·g−1 at 10 mV/s, surpassing both pure CCTO15Sr (80.19 mF·g−1) and CCTO15Sr-6GO (25.73 mF·g−1). These results stem from oxygen and metal vacancies, which aid charge accumulation and ion diffusion. In contrast, adding GO generally reduced specific capacitance in all samples. The findings highlight CCSTO’s potential—especially with rGO modification—as a supercapacitor electrode while also indicating areas for further optimization.