Removal of Diclofenac from Aqueous Solutions Using Surfactant-Modified Guava Seeds as Biosorbent

Abstract

The persistent pharmaceutical diclofenac (DCF) presents a significant environmental challenge due to its widespread presence and biological activity in water systems. This study aimed to develop and characterize a novel, low-cost biosorbent by modifying waste guava seeds (GS) with the cationic surfactant cetyltrimethylammonium bromide (CTAB) to enhance the removal of DCF from aqueous solutions. GS and seeds modified with CTAB at 2 mmol/L (MGS-2) and 10 mmol/L (MGS-10) were prepared and characterized using FTIR, SEM-EDS, TGA, and Zeta Potential measurements. Batch adsorption experiments were conducted to assess the effects of contact time, biosorbent dosage, and solution pH. CTAB modification changed the biosorbent’s surface charge from negative to positive, thereby enhancing DCF removal. The MGS-10 biosorbent demonstrated the fastest kinetics. Critically, an intermediate level of surfactant modification (MGS-2) proved optimal, achieving a maximum adsorption capacity of 38.0 mg/g at 45 °C. This capacity significantly surpassed both the GS (29.7 mg/g) and the MGS-10 (32.7 mg/g). This superior performance is attributed to a favorable multi-stage adsorption mechanism, which combines electrostatic attraction and hydrophobic interactions, and is determined to be an endothermic and entropy-driven process. While highly effective, the biosorbents showed poor regenerability with NaOH, indicating a need to explore alternative regeneration methods. This work demonstrates that optimally modified guava seeds are a promising and sustainable material for remediating pharmaceutical contaminants from water.