Triboelectric-Enhanced Piezoelectric Nanogenerator with Pressure-Processed Multi-Electrospun Fiber-Based Polymeric Layer for Wearable and Flexible Electronics

Abstract

A triboelectricity-enhanced piezoelectric nanogenerator (PENG) based on pressure-processed multi-electrospun polymeric layers is herein developed for efficient vibrational energy harvesting. The hybridization of piezoelectric and triboelectric mechanisms through electrospinning has been utilized to enhance electrical output by increasing contact areas and promoting alignment within piezoelectric materials. A multi-layer structure comprising alternating poly (vinylidene fluoride) (PVDF) and poly (hexamethylene adipamide) (PA 6/6) exhibits superior electrical performance. A lateral Janus configuration, providing distinct positive and negative triboelectric polarities, has further optimized device efficiency. This approach introduces a novel operational mechanism, enabling superior performance compared to conventional methods. The fiber-based architecture ensures exceptional flexibility, low weight, and a high surface-to-volume ratio, enabling enhanced energy harvesting. Experimentally, the PENG achieved an open-circuit voltage of 14.59 V, a short-circuit current of 205.7 nA, and a power density of 7.5 mW m−2 at a resistance of 30 MΩ with a five-layer structure subjected to post-processing under pressure. A theoretical model has mathematically elucidated the output results. Long-term durability (over 345,600 cycles) has confirmed its robustness. Demonstrations of practical applications include monitoring human joint motion and respiratory activity. These results highlight the potential of the proposed triboelectricity-enhanced PENG for vibrational energy harvesting in flexible and wearable electronic systems.