Degradation of Tetracycline Hydrochloride by Cobalt-Doped Biochar-Activated Peroxymonosulfate

Abstract

The presence of tetracycline hydrochloride (TC) in the environment poses significant risks to human health and ecological stability, necessitating the development of effective and rapid removal strategies. In this research, we investigate the efficacy of degrading tetracycline hydrochloride using cobalt-doped-biochar (Co-BC)-activated peroxymonosulfate (PMS) and the underlying mechanisms of this process. The research objectives and conclusions were as follows: (1) Co-BC materials were synthesized from balsa wood powder through a process of impregnation followed by high-temperature calcination. Characterization techniques such as SEM, XRD, FTIR, and XPS were used to confirm the material’s structure and composition. (2) In a TC solution of 20 mg L−1, the use of 100.0 mg L−1 of Co-BC and 1.0 mM PMS led to a TC degradation efficiency of 96.2% within 30 min. (3) The Co-BC+PMS system exhibited wide pH adaptability (4.34–9.02) and strong resistance to environmental matrix interference (Cl−, NO3−, and SO42−). (4) Free-radical quenching experiments indicated that sulfate radicals (SO4•−) were the primary reactive species in TC degradation. The 11 intermediates of TC were analyzed using LC-MS, and two possible degradation pathways were deduced. In summary, this study offers significant, valuable insights into and technical support for the green, efficient, and environmentally friendly removal of antibiotics from sewage.