Structural insights of mechanochemically amorphised MIL-125-NH2
E ShawCelia Castillo‐BlasTimothy LambdenBeatriz de SantosBethan TurnerGiulio I. LamprontiJoonatan E. M. LaulainenGeorgina P. RobertsonAshleigh M. ChesterChumei YeShaoliang GuanJoshua K G KarlssonValentina MartinezIvana BrekaloBahar KaradenizSilvia CabreraLauren McHughKrunoslav UžarevićJosé AlemánAlberto FraileRachel C. EvansPaul A. MidgleyDavid A. KeenXavier MoyaThomas D. Bennett
Abstract
Localised and bulk analyses of ball-milled amorphous MIL-125-NH2 revealed prolonged milling resulted in the loss of long-range structural order, partial retention of the local bonding, and the successive introduction of defects through metal-linker bond breakage.
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