Structural contributions of Zn in enhancing CO 2 hydrogenation to methanol over Zn x ZrO y catalysts

Zinat Zanganeh; Max L. Bols; Parviz Yazdani; Hilde Poelman; Mark Saeys

doi:10.1039/d4cy01175a

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Structural contributions of Zn in enhancing CO ₂ hydrogenation to methanol over Zn _x ZrO _y catalysts

Zinat Zanganeh Max L. Bols Parviz Yazdani Hilde Poelman Mark Saeys

Year: 2024 Journal: Catalysis Science & Technology Vol: 15 (2)Pages: 563-579 Publisher: Royal Society of Chemistry

DOI: 10.1039/d4cy01175a

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Abstract

While Zn and Zr are selective towards CO production, the addition of Zn to ZrO 2 shifts the selectivity to methanol by inducing a phase transformation from tetragonal to cubic ZrO 2 , enhancing methanol synthesis efficiency in CO 2 hydrogenation.

Keywords:

Methanol Olefin fiber Catalysis Chemistry Materials science Chemical engineering Organic chemistry

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Catalysts for Methane Reforming

Physical Sciences → Chemical Engineering → Catalysis

Carbon dioxide utilization in catalysis

Physical Sciences → Chemical Engineering → Process Chemistry and Technology

Catalytic Processes in Materials Science

Physical Sciences → Materials Science → Materials Chemistry

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Structural contributions of Zn in enhancing CO 2 hydrogenation to methanol over Zn x ZrO y catalysts

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