Multispin superatoms: seven-nuclear rhenium clusters with unusual magnetic properties

Aleksei S. Pronin; Yakov M. Gaifulin; Taisiya S. Sukhikh; А. Н. Лавров; Yuri V. Mironov

doi:10.1039/d4qi02353f

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Multispin superatoms: seven-nuclear rhenium clusters with unusual magnetic properties

Aleksei S. Pronin Yakov M. Gaifulin Taisiya S. Sukhikh А. Н. Лавров Yuri V. Mironov

Year: 2024 Journal: Inorganic Chemistry Frontiers Vol: 11 (24)Pages: 8945-8952 Publisher: Royal Society of Chemistry

DOI: 10.1039/d4qi02353f

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Abstract

Two seven-nuclear rhenium cluster complexes [{Re 3 S 4 (CN) 9 }{Re 4 S 4 }(CN) 9 ] 7− and [{Re 3 Se 4 (CN) 9 }{Re 4 Se 4 }(CN) 9 ] 7− with a new structural type and unique magnetic behavior have been synthesized.

Keywords:

Rhenium Materials science Chemical physics Nuclear magnetic resonance Chemistry Physics Metallurgy

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Inorganic Chemistry and Materials

Physical Sciences → Chemistry → Inorganic Chemistry

Magnetism in coordination complexes

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Nanocluster Synthesis and Applications

Physical Sciences → Materials Science → Materials Chemistry

Multispin superatoms: seven-nuclear rhenium clusters with unusual magnetic properties

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