Synthesis of ZnPc/BiVO4 Z-Scheme Heterojunction for Enhanced Photocatalytic Degradation of Tetracycline Under Visible Light Irradiation

Abstract

The construction of semiconductor heterojunctions is an effective strategy to improve the photocatalytic degradation efficiency of organic pollutants. Herein, ZnPc/BiVO4 Z-scheme heterojunction was synthesized via a physical mixing method and was used for the photocatalytic degradation of tetracycline (TC) under visible light irradiation. Compared with BiVO4 and ZnPc, the 15ZnPc/BiVO4 sample exhibited improved light absorption capacity, and the electron-hole separation efficiency and redox capacity were enhanced due to the formation of the Z-scheme heterojunction. The 15ZnPc/BiVO4 composite exhibited an optimal TC degradation rate of 83.1% within 120 min. Additionally, 15ZnPc/BiVO4 exhibited excellent stability in cycling experiments, which maintained a high TC degradation rate of 79.5% after four cycles. Free radical trapping experiments indicated that superoxide radicals (O2−) were the main active substances in the photocatalytic degradation of TC.