Volatile lanthanide complexes with fluorinated heptadentate ligands

Joshua C. Zgrabik; Balaka Bhuniya; Thomas Branstad Phillips; Jorge Barroso; Bess Vlaisavljevich; Scott R. Daly

doi:10.1039/d3dt04198k

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Volatile lanthanide complexes with fluorinated heptadentate ligands

Joshua C. Zgrabik Balaka Bhuniya Thomas Branstad Phillips Jorge Barroso Bess Vlaisavljevich Scott R. Daly

Year: 2024 Journal: Dalton Transactions Vol: 53 (7)Pages: 2998-3009 Publisher: Royal Society of Chemistry

DOI: 10.1039/d3dt04198k

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Abstract

Here we describe the synthesis, structures, and volatility of lanthanide complexes containing N 4 O 3 ligands decorated with different fluoroalkyl substituents. The results show how ligand fluorination does not necessarily enhance complex volatility.

Keywords:

Lanthanide Chemistry Coordination sphere Crystallography Lanthanide contraction Metal Molecule Ligand (biochemistry) Intermolecular force Sublimation (psychology) Crystal structure Ion Organic chemistry

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Inorganic Fluorides and Related Compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Fluorine in Organic Chemistry

Life Sciences → Pharmacology, Toxicology and Pharmaceutics → Pharmaceutical Science

Advanced Chemical Physics Studies

Physical Sciences → Physics and Astronomy → Atomic and Molecular Physics, and Optics

Volatile lanthanide complexes with fluorinated heptadentate ligands

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