Acetate ion addition to and exchange in (1,5-cyclooctadiene)rhodium(<scp>i</scp>) acetate: relevance for the coagulation of carboxylic acid-functionalized shells of core-crosslinked micelle latexes

Ambra Maria Fiore; Valentina Petrelli; Christophe Fliedel; Éric Manoury; Piero Mastrorilli; Rinaldo Poli

doi:10.1039/d3dt02260a

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Acetate ion addition to and exchange in (1,5-cyclooctadiene)rhodium(i) acetate: relevance for the coagulation of carboxylic acid-functionalized shells of core-crosslinked micelle latexes

Ambra Maria Fiore Valentina Petrelli Christophe Fliedel Éric Manoury Piero Mastrorilli Rinaldo Poli

Year: 2023 Journal: Dalton Transactions Vol: 52 (35)Pages: 12534-12542 Publisher: Royal Society of Chemistry

DOI: 10.1039/d3dt02260a

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Abstract

[Rh(COD)(μ-OAc)] 2 reacts with acetate in dichloromethane to produce equilibrium amounts of [Rh(COD)(OAc) 2 ] − and exchanges the acetate ligands with polymer-linked methacrylic acid, rationalizing the coagulation of core-crosslinked micelle latexes.

Keywords:

Chemistry Rhodium Polymer chemistry Nuclear magnetic resonance spectroscopy Organic chemistry Catalysis

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Surfactants and Colloidal Systems

Physical Sciences → Chemistry → Organic Chemistry

Advanced Polymer Synthesis and Characterization

Physical Sciences → Chemistry → Organic Chemistry

Lanthanide and Transition Metal Complexes

Physical Sciences → Materials Science → Materials Chemistry

Acetate ion addition to and exchange in (1,5-cyclooctadiene)rhodium(i) acetate: relevance for the coagulation of carboxylic acid-functionalized shells of core-crosslinked micelle latexes

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