Multidentate Ligand-Passivated CsPbI₃ Perovskite Nanocrystals for Stable and Efficient Red-Light-Emitting Diodes

Abstract

CsPbI₃ nanocrystals (NCs) have become a research hot spot in the field of light-emitting diodes (LEDs). Whereas, the long chain ligands with weak affinity to CsPbI₃ NCs have prevented their further development and commercialization. Herein, a novel multidentate short ligand tetramethylthiuram disulfide (TMTD) was employed via a ligand exchange process to enhance hole mobility and decrease trap density of the CsPbI₃ NCs film. Therefore, TMTD passivated CsPbI₃ NCs LED exhibited 20.65% maximum external quantum efficiency and 3861 cd/m² maximum luminance. Furthermore, TMTD passivated CsPbI₃ NCs LED exhibited good operational stability with a 128 min half-lifetime. This strategy using multidentate short ligand passivation provides an effective way to promote perovskite LED development and commercialization.