JOURNAL ARTICLE

Photo-ageing of Poly(Butylene Terephthalate) and Poly(Butylene Terephthalate)-Fibre Glass Systems

Jean‐Luc Gardette

Year: 1997 Journal:   Polymers and Polymer Composites Vol: 5 (1)Pages: 7-13   Publisher: SAGE Publishing

Abstract

The photolysis and photo-oxidation mechanisms of poly(butylene terephthalate) (PBT) and poly(butylene terephthalate)-fibre glass (PBT-FG) irradiated under polychromatic light (λ ≥ 2300 nm) were studied. Derivatisation reactions coupled to FTIR analysis of the exposed samples permitted the identification of the various photo-products and the proposal of mechanisms. It was found that the same photo-products were formed in PBT and PBT-FG. Micro-FTIR analysis of the irradiated samples showed that the photochemical reactions were limited to a depth of 50 urn from the exposed surface, both in PBT and PBT-FG.

Keywords:
Materials science Fourier transform infrared spectroscopy Irradiation Poly ethylene Photodissociation Polymer chemistry Composite material Ethylene Chemical engineering Photochemistry Chemistry Catalysis Organic chemistry

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Topics

Polymer crystallization and properties
Physical Sciences →  Materials Science →  Polymers and Plastics
Surface Modification and Superhydrophobicity
Physical Sciences →  Materials Science →  Surfaces, Coatings and Films
Fiber-reinforced polymer composites
Physical Sciences →  Engineering →  Mechanical Engineering

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