Electrochemical Co-reduction of N₂ and CO₂ to Urea Using Bi₂S₃ Nanorods Anchored to N-Doped Reduced Graphene Oxide

Abstract

Producing "green urea" using renewable energy, N₂, and CO₂ is a long-considered challenge. Herein, an electrocatalyst, Bi₂S₃/N-reduced graphene oxide (RGO), was synthesized by loading the Bi₂S₃ nanorods onto the N-RGO via a hydrothermal method. The Bi₂S₃/N-RGO composites exhibit the highest yield of urea (4.4 mmol g^-1 h^-1), which is 12.6 and 3.1 times higher than that of Bi₂S₃ (0.35 mmol g^-1 h^-1) and that of N-RGO (1.4 mmol g^-1 h^-1), respectively. N-RGO, because of its porous and open-layer structure, improves the mass transfer efficiency and stability, while the basic groups (-OH and -NH₂) promote the adsorption and activation of CO₂. Bi₂S₃ promotes the absorption and activation of inert N₂. Finally, the defect sites and the synergistic effect on the Bi₂S₃/N-RGO composites work simultaneously to form urea from N₂ and CO₂. This study provides new insights into urea synthesis under ambient conditions and a strategy for the design and development of a new material for green urea synthesis.