Pentacarbonyl-1κ2C,2κ3C-(μ-ethyl 3-mercaptopropionato-1κS:2κS)(μ-4-methylbenzoyl-1κO:2κC)(triphenylphosphine-1κP)diiron(Fe—Fe)

Jinting Liu; Yuchang Du; Yan-Jun Mao; Lei Zhang; Yun‐Long Wu

doi:10.1107/s1600536806006647

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Pentacarbonyl-1κ²C,2κ³C-(μ-ethyl 3-mercaptopropionato-1κS:2κS)(μ-4-methylbenzoyl-1κO:2κC)(triphenylphosphine-1κP)diiron(Fe—Fe)

Jinting Liu Yuchang Du Yan-Jun Mao Lei Zhang Yun‐Long Wu

Year: 2006 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 62 (3)Pages: m642-m644 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536806006647

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Abstract

In the molecule of the title compound, [Fe2(C8H7O)(C5H9O2S)(C18H15P)(CO)5], the two Fe atoms are bridged by the ethyl 3-mercaptopropionate and 4-methylbenzoyl ligands. The central structural Fe2COS fragment adopts an envelope conformation. Each Fe atom is in a pseudo-square pyramidal coordination. In addition, the crystal structure is stabilized by intermolecular C—H⋯O hydrogen bonds.

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Chemistry Physics Radiochemistry

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