Sodium Alginate-Based Carbon Aerogel-Supported ZIF-8-Derived Porous Carbon as an Effective Adsorbent for Methane Gas

Abstract

Adsorption natural gas (ANG) is a technology in which natural gas is stored on the surface of porous materials at relatively low pressures, which are promising candidates for adsorption of natural gas. Adsorbent materials with a large surface area and porous structure plays a significant role in the ANG technology, which holds promise in increasing the storage density for natural gas while decreasing the operating pressure. Here, we demonstrate a facile synthetic method for rational construction of a sodium alginate (SA)/ZIF-8 composite carbon aerogel (AZSCA) by incorporating ZIF-8 particles into SA aerogel through a directional freeze-drying method followed by the carbonization process. The structure characterization shows that AZSCA has a hierarchical porous structure, in which the micropores originated from MOF while the mesopores are derived from the three-dimensional network of the aerogel. The experimental results show that AZSCA achieved high methane adsorption of 181 cm³·g^-1 at 65 bar and 298 K, along with higher isosteric heat of adsorption (Q_st) throughout the adsorption range. Thus, the combination of MOF powders with aerogel can find potential applications in other gas adsorption.