Cd[B2(SO4)4] and H2[B2(SO4)4] – a phyllosilicate-analogous borosulfate and its homeotypic heteropolyacid

Matthias Hämmer; Leonard C. Pasqualini; Sean S. Sebastian; Hubert Huppertz; Henning A. Höppe; Jörn Bruns

doi:10.1039/d2dt02344j

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Cd[B₂(SO₄)₄] and H₂[B₂(SO₄)₄] – a phyllosilicate-analogous borosulfate and its homeotypic heteropolyacid

Matthias Hämmer Leonard C. Pasqualini Sean S. Sebastian Hubert Huppertz Henning A. Höppe Jörn Bruns

Year: 2022 Journal: Dalton Transactions Vol: 51 (40)Pages: 15458-15466 Publisher: Royal Society of Chemistry

DOI: 10.1039/d2dt02344j

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Abstract

The phyllosilicate-analoguous borosulfate H 2 [B 2 (SO 4 ) 4 ] and its cadmium salt, Cd[B 2 (SO 4 ) 4 ], have been synthesized via various paths and analyzed thoroughly. The heteropolyacid is the second structurally determined acid within borosulfate chemistry.

Keywords:

Thermogravimetry Crystallography Metal Single crystal Silicate Chemistry Diffraction X-ray crystallography Crystal structure Powder diffraction Spectroscopy Infrared spectroscopy Materials science Inorganic chemistry Physics Optics

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Crystal Structures and Properties

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Polyoxometalates: Synthesis and Applications

Physical Sciences → Materials Science → Materials Chemistry

Chemical Synthesis and Characterization

Physical Sciences → Environmental Science → Industrial and Manufacturing Engineering

Cd[B₂(SO₄)₄] and H₂[B₂(SO₄)₄] – a phyllosilicate-analogous borosulfate and its homeotypic heteropolyacid

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