Hierarchical Hollow CoWO₄–Co(OH)₂ Heterostructured Nanoboxes Enabling Efficient Water Oxidation Electrocatalysis

Abstract

Rational design and construction of well-defined hollow heterostructured nanomaterials assembled by ultrathin nanosheets overtakes crucial role in developing high-efficiency oxygen evolution reaction (OER) electrocatalysts. Herein, a reliable metal-organic framework-mediated and cation-exchange strategy to tune the geometric structure and multicomponent heterostructures has been proposed for the fabrication of hollow CoWO₄-Co(OH)₂ hierarchical nanoboxes assembled by rich ultrathin nanosheets. Benefiting from the hierarchical hollow nanostructure, the CoWO₄-Co(OH)₂ nanoboxes offer plenty of metal active centers available for reaction intermediates. Moreover, the well-defined nanointerfaces between CoWO₄ and Co(OH)₂ can function as the bridge for boosting the efficient electron transfer from CoWO₄ to Co(OH)₂. As a consequence, the optimized CoWO₄-Co(OH)₂ nanoboxes can exhibit outstanding electrocatalytic performance toward OER by delivering 10 mA cm^-2 with a low overpotential of 280 mV and a small Tafel slope of 70.6 mV dec^-1 as well as outstanding electrochemical stability. More importantly, this CoWO₄-Co(OH)₂ heterostructured nanocatalyst can couple with Pt/C to drive overall water splitting to achieve 10 mA cm^-2 with a voltage of 1.57 V.