Preparation and Structure of [Na.15-crown-5][Ni(mnt)<sub>2</sub>].H<sub>2</sub>O

Neil Robertson; Stefan Roehrs; Tomoyuki Akutagawa; Takayoshi Nakamura; Allan E. Underhill

doi:10.1177/174751989902300133

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Preparation and Structure of [Na.15-crown-5][Ni(mnt)₂].H₂O

Neil Robertson Stefan Roehrs Tomoyuki Akutagawa Takayoshi Nakamura Allan E. Underhill

Year: 1999 Journal: Journal of Chemical Research Vol: 23 (1)Pages: 54-55 Publisher: SAGE Publishing

DOI: 10.1177/174751989902300133

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Abstract

The salt [Na.15-crown-5][Ni(mnt)2].H 2 O has been prepared by electrocrystallisation and characterised by X-ray crystallography showing a stacking arrangement of [Ni(mnt) 2 ] - and a slipped stack arrangement of the crown ethers.

Keywords:

Stacking Crown (dentistry) Crystallography Stack (abstract data type) Crystal structure Salt (chemistry) Chemistry Materials science Computer science Physical chemistry Operating system Composite material

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Polyoxometalates: Synthesis and Applications

Physical Sciences → Materials Science → Materials Chemistry

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Preparation and Structure of [Na.15-crown-5][Ni(mnt)₂].H₂O

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