JOURNAL ARTICLE

1,4-Bis[(2,2′:6′,2′′-terpyridin-4′-yl)oxy]butane

Matthew P. AkermanCraig D. GrimmerVarvara I. NikolayenkoDesigan Reddy

Year: 2011 Journal:   Acta Crystallographica Section E Structure Reports Online Vol: 67 (12)Pages: o3478-o3479   Publisher: International Union of Crystallography

Abstract

The title compound, C(34)H(28)N(6)O(2), has an inversion centre located at the mid-point of the central C-C bond of the diether bridging unit. The central pyridine rings of the terpyridyl units and the diether chain are co-planar: the maximum deviation from the 18-atom mean plane defined by the bridging unit and the central pyridyl ring is for the pyridyl N atom which sits 0.055 (1) Å above the plane. The dihedral angles between the terminal pyridine rings with this plane are 10.3 (1) and 37.6 (1)°, repectively. In the crystal, weak C-H⋯N inter-actions link the mol-ecules into infinite chains parallel to the a axis.

Keywords:
Dihedral angle Chemistry Crystallography Pyridine Ring (chemistry) Planar Butane Atom (system on chip) Unit (ring theory) Plane (geometry) Stereochemistry Hydrogen bond Geometry Molecule Medicinal chemistry Mathematics Organic chemistry

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Citation History

Topics

Crystal structures of chemical compounds
Physical Sciences →  Chemistry →  Inorganic Chemistry
Crystallography and molecular interactions
Physical Sciences →  Chemistry →  Physical and Theoretical Chemistry
Synthesis and Characterization of Heterocyclic Compounds
Physical Sciences →  Chemistry →  Organic Chemistry

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