JOURNAL ARTICLE
ChemInform Abstract: Mechanisms for the Solvolytic Decompositions of Nucleoside Analogues. Part 9. Pathways for the Alkaline Hydrolysis of 6‐Substituted 9‐(1‐Ethoxyethyl)purines.
H. LOENNBERGPertti LehikoinenKari Neuvonen
Year: 1983 Journal: Chemischer Informationsdienst Vol: 14 (14) Publisher: Wiley
Abstract
Abstract Die aus 1‐Chlor‐diethylether und den entsprechenden Purinen hergestellten Titelverbindungen (I) erfahren bei ihrer basischen Hydrolyse durch nucleophilen Angriff am C(8)‐Atom eine Spaltung zum Diamin (II) und dem Methylpurin (III) als Hauptprodukten.
Keywords:
Chemistry Nucleoside Alkaline hydrolysis Purine metabolism Hydrolysis Purine Nitrogen atom Medicinal chemistry Stereochemistry Biochemistry Organic chemistry Enzyme Ring (chemistry)
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