JOURNAL ARTICLE

(4,4′-Bipyridine)dichloromanganese(II), a two-dimensional coordination polymer

Ann M. ChippindaleA.R. CowleyKatherine J. Peacock

Year: 2000 Journal:   Acta Crystallographica Section C Crystal Structure Communications Vol: 56 (6)Pages: 651-652   Publisher: Wiley

Abstract

The title compound, [MnCl2(C10H8N2)]n, crystallizes with a two-dimensional network constructed from linear chains of edge-sharing MnCl4 square-planar units cross-linked by bidentate 4,4′-bi­pyridine bridges. The Mn atom and the bipyridine moieties lie on sites with 222 crystallographic symmetry; the Cl atom lies on a twofold axis. The bi­pyridine mol­ecule is twisted about the central C—C bond by 33.5 (3)°.

Keywords:
4,4'-Bipyridine Bipyridine Coordination polymer Polymer Chemistry Materials science Crystallography Organic chemistry Molecule Crystal structure Hydrogen bond

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Topics

Metal-Organic Frameworks: Synthesis and Applications
Physical Sciences →  Chemistry →  Inorganic Chemistry
Crystal structures of chemical compounds
Physical Sciences →  Chemistry →  Inorganic Chemistry
Magnetism in coordination complexes
Physical Sciences →  Materials Science →  Electronic, Optical and Magnetic Materials

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