Strongly Coupled Tin(IV) Sulfide–MultiWalled Carbon Nanotube Hybrid Composites and Their Enhanced Thermoelectric Properties

Abstract

Herein, tin(IV) sulfide (SnS₂) and multiwalled carbon nanotube (MWCNT) composites are fabricated via a simple solution-mixing method in a hydrothermal reactor. SnS₂ is closely coupled to the MWCNT surface, thus forming a coaxial nanostructure. Examination by X-ray photoelectron spectroscopy and scanning transmission electron microscopy indicates that the strong interface between SnS₂ and the MWCNTs in the composite material is due to the formation of Sn-O and Sn-S bonds. In addition, an examination of the temperature-dependent thermoelectric (TE) properties demonstrates that the SnS₂-MWCNT hybrid composite with 3 wt % MWCNTs exhibits the maximum power factor of ∼91.34 μW/(m·K²) at 500 K, which is ∼50 times larger than that of the pristine SnS₂. These results highlight the fabrication and enhanced TE properties of hybrid composites via the coupling of SnS₂ and MWCNTs.