JOURNAL ARTICLE
有机同系物分子均衡化学势与电离能
Year: 1995 Journal: Science in China Series B-Chemistry Life Sciences & Earth Sciences (in Chinese) Publisher: Science China Press
Abstract
有机同系物的电离能Ip可表示为:Ip=(∑Xi)/(a+bn),其中Xi为组成同系物分子的各原子的电负性(基态下价电子能量平均值),n为重复单元的重复度,(a+bn)为分子轨道中电子运动的范围. 将=(∑Xi)/Ip对n进行线性回归分析,结果42个同系列146组光电子能谱数据列,相关系数r全部大于0.990,优秀率达100％.
Keywords:
Uranium-238 Physics
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Topics
Free Radicals and Antioxidants
Physical Sciences → Chemistry → Organic Chemistry
Molecular spectroscopy and chirality
Physical Sciences → Chemistry → Spectroscopy
Various Chemistry Research Topics
Physical Sciences → Chemistry → Physical and Theoretical Chemistry
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