BOOK-CHAPTER
6 Proton-Coupled Electron Transfer
Abstract
Abstract Proton-coupled electron transfer (PCET) enables the functionalization of prevalent organic moieties that are commonly regarded as energetically inaccessible. This chapter focuses on reductive and oxidative PCET in organic systems and the variety of catalyst systems that allow for the formation of ketyl and amidyl radicals for C–C and C–N bond-forming reactions.
Keywords:
Proton-coupled electron transfer Ketyl Electron transfer Radical Proton Photochemistry Electron Chemistry Catalysis Organic synthesis Combinatorial chemistry Organic chemistry Physics Nuclear physics
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Topics
Metal-Catalyzed Oxygenation Mechanisms
Physical Sciences → Chemistry → Inorganic Chemistry
Catalytic C–H Functionalization Methods
Physical Sciences → Chemistry → Organic Chemistry
Radical Photochemical Reactions
Physical Sciences → Chemistry → Organic Chemistry
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