Angle-Dependent Polarized Emission and Photoelectron Performance of Dye-Encapsulated Metal–Organic Framework

Abstract

Molecule-based crystalline materials with angle-dependent polarized emission have attracted considerable attention owing to their extensive applications in displays and anticounterfeiting. Herein, one anionic metal-organic framework (MOF) {[Zn_2.5(μ₃-OH)(NDC)₂(HNDC)](HPIM)}_n was constructed on the basis of an excellent photoactive ligand naphthalene-1,4-dicarboxylic acid (H₂NDC). The protonated 2-propylimidazole (HPIM) guests residing in the nanochannels of MOF can be exchanged by a D-π-A cationic dye. The resulted host-guest system shows a rare example of ratiometric fluorescent polarizations and highly enhanced photoelectron performance in comparison with the pristine MOF.