Enantioselective preparation of atropisomeric biaryl trifluoromethylsulfanes <i>via</i> ring-opening of cyclic diaryliodoniums

Longhui Duan; Zhonggui Wang; Kun Zhao; Zhenhua Gu

doi:10.1039/d1cc00171j

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Enantioselective preparation of atropisomeric biaryl trifluoromethylsulfanes via ring-opening of cyclic diaryliodoniums

Longhui Duan Zhonggui Wang Kun Zhao Zhenhua Gu

Year: 2021 Journal: Chemical Communications Vol: 57 (32)Pages: 3881-3884 Publisher: Royal Society of Chemistry

DOI: 10.1039/d1cc00171j

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Abstract

Two convenient and practical methods for the synthesis of axially chiral biaryls bearing the trifluoromethylthio group are reported.

Keywords:

Enantioselective synthesis Axial symmetry Ring (chemistry) Chemistry Combinatorial chemistry Atropisomer Catalysis Organic chemistry Mathematics

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Axial and Atropisomeric Chirality Synthesis

Physical Sciences → Chemistry → Organic Chemistry

Asymmetric Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Catalytic C–H Functionalization Methods

Physical Sciences → Chemistry → Organic Chemistry

Enantioselective preparation of atropisomeric biaryl trifluoromethylsulfanes via ring-opening of cyclic diaryliodoniums

Abstract

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Citation History

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Enantioselective preparation of atropisomeric biaryl trifluoromethylsulfanes via ring-opening of cyclic diaryliodoniums

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