Sacrifice Template Strategy to the Fabrication of a Self-Cleaning Nanofibrous Membrane for Efficient Crude Oil-in-Water Emulsion Separation with High Flux

Abstract

The superhydrophilic/underwater superoleophobic membrane materials have attracted considerable attention in oil/water separation. However, most materials are extremely susceptible to pollution during oil-water separation, which drastically restricts their widespread applications. Herein, a momordica-charantia-like nanofibrous membrane (MCNM) with underwater superoleophobic performance was fabricated through a sacrifice template strategy by the electrospinning solution of zeolitic imidazolate framework-8 (ZIF-8) and polyacrylonitrile particles. The opened voids and wrinkles left after removing the template of nanocrystals ZIF-8 not only increased the porosity and roughness of the as-prepared fibrous membrane but also tremendously improved the underwater superoleophobicity. Therefore, the as-prepared MCNM showed excellent self-cleaning performance toward crude oil under water, avoiding the decrease of the separation efficiency and flux caused by membrane fouling during oil-water separation. Meanwhile, the separation efficiency of various surfactant-stabilized oil-in-water emulsions was higher than 99.6% with a flux up to 1580 ± 30 L m^-2 h^-1 solely driven by gravity. Moreover, no obvious wrinkles and cracks were observed on the resulted nanofibrous membrane after the sand impact and bent testing. More importantly, the as-prepared MCNM still maintained exceptional underwater superoleophobicity in harsh environment (3.5 wt % NaCl, 4 M HCl, 50 °C hot water) even after ultrasound for 1 h. The robust mechanical and chemical stability makes the antifouling MCNM exhibit tremendous potential for practical applications in dealing with oily wastewater in the future.