Buckle-Delamination-Enabled Stretchable Silver Nanowire Conductors

Abstract

Controlled buckling and delamination of thin films on a compliant substrate has attracted much attention for applications ranging from micro/nanofabrication to flexible and stretchable electronics to bioengineering. Here, a highly conductive and stretchable conductor is fabricated by attaching a polymer composite film (with a thin layer of silver nanowires embedded below the surface of the polymer matrix) on top of a prestretched elastomer substrate followed with releasing the prestrain. A partially delaminated wavy geometry of the polymer film is created. During the evolution of the buckle-delamination, the blisters pop-up randomly but self-adjust into a uniform distribution, which effectively reduces the local strain in the silver nanowires. The resistance change of the conductor is less than 3% with the applied strain up to 100%. A theoretical model on the buckle-delamination structure is developed to predict the geometrical evolution, which agrees well with experimental observation. Finally, an integrated silver nanowire/elastomer sensing module and a stretchable thermochromic device are developed to demonstrate the utility of the stretchable conductor. This work highlights the important relevance of mechanics-based design in nanomaterial-enabled stretchable devices.