Chiral tetranuclear copper(<scp>ii</scp>) complexes: synthesis, optical and magnetic properties

Naushad Ahmed; Shalini Tripathi; Arup Sarkar; Kamal Uddin Ansari; Chinmoy Das; Neetu Prajesh; Satoshi Horike; Ramamoorthy Boomishankar; Maheswaran Shanmugam

doi:10.1039/d0nj02856h

JOURNAL ARTICLE

Chiral tetranuclear copper(ii) complexes: synthesis, optical and magnetic properties

Naushad Ahmed Shalini Tripathi Arup Sarkar Kamal Uddin Ansari Chinmoy Das Neetu Prajesh Satoshi Horike Ramamoorthy Boomishankar Maheswaran Shanmugam

Year: 2020 Journal: New Journal of Chemistry Vol: 44 (39)Pages: 16845-16855 Publisher: Royal Society of Chemistry

DOI: 10.1039/d0nj02856h

Get Full-Text PDF Get Analytical Report

Abstract

The chiral tetranuclear Cu(ii) cubane complexes with the general molecular formula [Cu₄(R-L₁)₄] (R-1) and [Cu₄(S-L₁)₄] (S-1) exhibit ferromagnetic exchange coupling, which is in contrast to the literature reports. This is corroborated by theoretical calculations.

Keywords:

Chemistry Cubane Copper Ferromagnetism Crystallography Coupling (piping) Stereochemistry Condensed matter physics Crystal structure Organic chemistry Metallurgy

Metrics

Cited By

0.43

FWCI (Field Weighted Citation Impact)

Refs

0.51

Citation Normalized Percentile

Is in top 1%

Is in top 10%

Citation History

Topics

Magnetism in coordination complexes

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Lanthanide and Transition Metal Complexes

Physical Sciences → Materials Science → Materials Chemistry

Metal-Catalyzed Oxygenation Mechanisms

Physical Sciences → Chemistry → Inorganic Chemistry

Chiral tetranuclear copper(ii) complexes: synthesis, optical and magnetic properties

Abstract

Metrics

Citation History

Topics

Related Documents

Tetranuclear Cu(ii)-chiral complexes: synthesis, characterization and biological activity

Synthesis, characterization and magnetic properties of halogenated tetranuclear cubane-like nickel(ii) complexes

Phenylmalonate‐Containing Copper(II) Complexes: Synthesis, Crystal Structure and Magnetic Properties

Synthesis and magnetic properties of some chiral tetranuclear imino-alkoxy complexes of copper(II)

Guanine-containing copper(ii) complexes: synthesis, X-ray structures and magnetic properties