Ligand engineering in Cu( <scp>ii</scp> ) paddle wheel metal–organic frameworks for enhanced semiconductivity

Matthias Golomb; Joaquín Calbo; Jessica K. Bristow; Aron Walsh

doi:10.1039/d0ta04466k

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Ligand engineering in Cu( ii ) paddle wheel metal–organic frameworks for enhanced semiconductivity

Matthias Golomb Joaquín Calbo Jessica K. Bristow Aron Walsh

Year: 2020 Journal: Journal of Materials Chemistry A Vol: 8 (26)Pages: 13160-13165 Publisher: Royal Society of Chemistry

DOI: 10.1039/d0ta04466k

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Abstract

We report the electronic structure of two metal–organic frameworks with copper paddle wheel nodes connected by a ligand with accessible nitrogen lone pairs. Our study highlights DMOF-1 as a potential semiconductor.

Keywords:

Ligand (biochemistry) Metal-organic framework Copper Lone pair Materials science Semiconductor Chemical engineering Chemistry Nanotechnology Optoelectronics Engineering Molecule Receptor Organic chemistry Metallurgy

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Metal-Organic Frameworks: Synthesis and Applications

Physical Sciences → Chemistry → Inorganic Chemistry

Magnetism in coordination complexes

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Nanocluster Synthesis and Applications

Physical Sciences → Materials Science → Materials Chemistry

Ligand engineering in Cu( ii ) paddle wheel metal–organic frameworks for enhanced semiconductivity

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