Fluorine-Doped Carbon Coated LiFePO3.938F0.062 Composites as Cathode Materials for High-Performance Lithium-Ion Batteries

Abstract

Fluorine-doped carbon coated olivine LiFePO3.938F0.062 composite (LFPF/CF) is synthesized by a simple solid-state reaction method, and the Tween40 and polyvinylidene fluoride (-(CH2-CF2)n-, PVDF) were used as carbon source and fluorine sources, respectively. Benefiting from the Tween40 (C22H42O6(C2H4O)n) is attributed to formation a homogeneous carbon layer on the surface of LiFePO4 particles. And polyvinylidene fluoride could produces fluoride in the thermal decomposition process, which is doped into carbon and LiFePO4 to form fluoride-doped carbon layer and LiFePO3.938F0.062, respectively. In this constructed architecture, the F-doped carbon layer acts as conductive network for LFP, which can enhance the electronic conductivity of overall electrode. Furthermore, the crystal lattice of LFP was enlarged by the F doping, which facilitates the Li+ intercalation/deintercalation. On the other hand, a strong electronic coupling between F-doped carbon and LiFePO3.938F0.062 can effectively suppress the shedding of carbon layer during cycling process, which keep stabilized of the reaction interface, and thus enhance the cycling stability. As a result, LFPF/CF composite shows superior rate performance (164.8, 159.2, 148.6, 135.8, and 102.3 mAh g−1 at 0.1, 0.5, 1, 5, and 10 C), and excellent cycling stability (high capacity retention of 95.6% after 500 cycles at high rate of 5 C).