JOURNAL ARTICLE
Nickel-Catalyzed Asymmetric Hydrocyanation of Allenes
Jinguo LongJihui GaoXianjie Fang
Year: 2020 Journal: Organic Letters Vol: 22 (2)Pages: 376-380 Publisher: American Chemical Society
Abstract
The first catalytic enantioselective hydrocyanation of allenes catalyzed by a (R,R)-Ph-BPE-Ni(0) complex catalyst has been accomplished. Numerous optically active allylic nitriles were obtained in good yield with excellent enantioselectivities (up to 98% ee).
Keywords:
Hydrocyanation Chemistry Enantioselective synthesis Catalysis Yield (engineering) Nickel Allylic rearrangement Organic chemistry Optically active Combinatorial chemistry Metallurgy
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39
Cited By
3.81
FWCI (Field Weighted Citation Impact)
63
Refs
0.92
Citation Normalized Percentile
Is in top 1%
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Citation History
Topics
Catalytic C–H Functionalization Methods
Physical Sciences → Chemistry → Organic Chemistry
Asymmetric Hydrogenation and Catalysis
Physical Sciences → Chemistry → Inorganic Chemistry
Catalytic Alkyne Reactions
Physical Sciences → Chemistry → Organic Chemistry
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