Experimental Analysis of the Extensional Flow of Very Weakly Viscoelastic Polymer Solutions

Abstract

We study with ultra-high-speed imaging the thinning of the filament formed during the breakup of a pendant droplet of very weakly viscoelastic polymer solutions of polyvinylpyrrolidone (PVP) and polyethylene oxide (PEO). In the latter case, we consider two molecular weights: 10 5 g/mol (PEO100K) and 2 × 10 6 g/mol (PEO2M). The results allow us to measure with high reproducibility extensional relaxation times of the order of 10 μ s. Despite the noticeable differences between PVP and PEO100K, very similar values are obtained for the range of concentrations where the linear elasto-capillary is established. For PEO2M, the extensional relaxation time depends on the concentration even for values significantly smaller than the overlap one. The prediction c low for the concentration below which the linear elasto-capillary regime cannot be reached qualitatively agrees with the results for PVP and PEO2M, while it underestimates the critical concentration for PEO100K. The results for PEO2M are consistent with those reported in the literature for higher concentrations.