Low-coordinate first-row transition metal complexes in catalysis and small molecule activation

Laurence J. Taylor; Deborah L. Kays

doi:10.1039/c9dt02402f

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Low-coordinate first-row transition metal complexes in catalysis and small molecule activation

Laurence J. Taylor Deborah L. Kays

Year: 2019 Journal: Dalton Transactions Vol: 48 (33)Pages: 12365-12381 Publisher: Royal Society of Chemistry

DOI: 10.1039/c9dt02402f

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Abstract

In this Perspective, we will highlight selected examples of transition metal complexes with low coordination numbers whose high reactivity has been exploited in catalysis and the activation of small molecules featuring strong bonds (N₂, CO₂, and CO).

Keywords:

Transition metal Catalysis Molecule Chemistry Metal Crystallography Stereochemistry Computational chemistry Photochemistry Chemical physics Organic chemistry

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Asymmetric Hydrogenation and Catalysis

Physical Sciences → Chemistry → Inorganic Chemistry

Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Carbon dioxide utilization in catalysis

Physical Sciences → Chemical Engineering → Process Chemistry and Technology

Low-coordinate first-row transition metal complexes in catalysis and small molecule activation

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