JOURNAL ARTICLE

Removal of phosphate and nitrate ions aqueous using strontium magnetic graphene oxide nanocomposite: Isotherms, kinetics, and thermodynamics studies

Abstract

Abstract Magnetic Fe 3 O 4 nanoparticle decorated graphene oxide (GO) was modified with strontium nanoparticles (MGO‐Sr) and applied for enhanced removal of phosphate and nitrate ions from river and sewage water samples. The nanocomposite's features were investigated using Fourier transform‐infrared spectrometry, field emission‐scanning electron microscopy, energy‐dispersive X‐ray spectroscopy, and X‐ray diffraction. The effective parameters, adsorption efficiency, regeneration, and field application of MGO‐Sr were also studied. Adsorption isotherm and kinetic models were applied for evaluation of experimental adsorption process. The data was in well comply with Langmuir isotherm and pseudo‐second‐order comparing with other models. Langmuir maximum adsorption capacity was obtained equal to 238.09 mg/g for phosphate and 357.14 mg/g for nitrate. Van't Hoff thermodynamic predicted an exothermic nature for adsorption process followed by a physisorption mechanism. The prepared nanocomposite provided a high‐removal efficiency toward phosphate and nitrate ions in river and sewage water. Hence, it is applicable in water remediation process.

Keywords:
Adsorption Physisorption Nanocomposite Langmuir adsorption model Graphene Aqueous solution Oxide Chemical engineering Materials science Inorganic chemistry Chemistry Physical chemistry Nanotechnology Organic chemistry

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51
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5.64
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72
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0.95
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Citation History

Topics

Phosphorus and nutrient management
Physical Sciences →  Environmental Science →  Industrial and Manufacturing Engineering
Adsorption and biosorption for pollutant removal
Physical Sciences →  Environmental Science →  Water Science and Technology
Iron oxide chemistry and applications
Physical Sciences →  Energy →  Renewable Energy, Sustainability and the Environment
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