ChemInform Abstract: Structural Features of Two Novel Alluaudite‐Like Arsenates Cd1.16Zn2.34(AsO4)1.5 (HAsO4)(H2AsO4)0.5 and Cd0.74Mg2.76(AsO4)1.5 (HAsO4)(H2AsO4)0.5.

Jovica Stojanović; Tamara Đorđević; Ljiljana Karanović

doi:10.1002/chin.201219013

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ChemInform Abstract: Structural Features of Two Novel Alluaudite‐Like Arsenates Cd_1.16Zn_2.34(AsO₄)_1.5 (HAsO₄)(H₂AsO₄)_0.5 and Cd_0.74Mg_2.76(AsO₄)_1.5 (HAsO₄)(H₂AsO₄)_0.5.

Jovica Stojanović Tamara Đorđević Ljiljana Karanović

Year: 2012 Journal: ChemInform Vol: 43 (19) Publisher: Wiley

DOI: 10.1002/chin.201219013

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Abstract

Abstract Single crystals of the new compounds Cd 1.16 Zn 2.34 (AsO 4 ) 1.5 (HAsO 4 )(H 2 AsO 4 ) 0.5 (I) and Cd 0.74 Mg 2.76 (AsO 4 ) 1.5 (HAsO 4 )(H 2 AsO 4 ) 0.5 (II) are hydrothermally synthesized from aqueous mixtures of Cd(OH) 2 , 5ZnO·2CO 3 ·4H 2 O, and As 2 O 5 in a molar ratio of 1:1:1 for (I) and Cd(OH) 2 , MgO, and As 2 O 5 in a molar ratio of 1:2:1 for (II) (autoclave, 473—493 K, 72—96 h, <50% yield).

Keywords:

Chemistry Autoclave Molar ratio Yield (engineering) Aqueous solution Crystallography Nuclear chemistry Metallurgy Physical chemistry Organic chemistry Materials science Catalysis

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ChemInform Abstract: Structural Features of Two Novel Alluaudite‐Like Arsenates Cd_1.16Zn_2.34(AsO₄)_1.5 (HAsO₄)(H₂AsO₄)_0.5 and Cd_0.74Mg_2.76(AsO₄)_1.5 (HAsO₄)(H₂AsO₄)_0.5.

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