ChemInform Abstract: Flavin‐Catalyzed Oxidation of Amines and Sulfur Compounds with Hydrogen Peroxide.

Shun‐Ichi Murahashi; Takeshi Oda; Yoshiyuki Masui

doi:10.1002/chin.198939092

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ChemInform Abstract: Flavin‐Catalyzed Oxidation of Amines and Sulfur Compounds with Hydrogen Peroxide.

Shun‐Ichi Murahashi Takeshi Oda Yoshiyuki Masui

Year: 1989 Journal: ChemInform Vol: 20 (39) Publisher: Wiley

DOI: 10.1002/chin.198939092

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Abstract

Abstract Treatment of 4a‐hydroxy‐5‐ethylflavin (4a‐FlEtOH) with 30% aqueous H 2 O 2 (10 equiv.) in MeOH leads to 4a‐FlEtOOH in 82% isolated yield which effects monooxidation of substrates by returning to 4a‐FlEtOH.

Keywords:

Chemistry Hydrogen peroxide Yield (engineering) Sulfur Catalysis Aqueous solution Flavin group Organic chemistry Medicinal chemistry Enzyme

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Chemical Synthesis and Reactions

Physical Sciences → Chemistry → Organic Chemistry

Organic Chemistry Cycloaddition Reactions

Physical Sciences → Chemistry → Organic Chemistry

Sulfur-Based Synthesis Techniques

Physical Sciences → Chemistry → Organic Chemistry

ChemInform Abstract: Flavin‐Catalyzed Oxidation of Amines and Sulfur Compounds with Hydrogen Peroxide.

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