The (SO2)2N3- Anion

Karl O. Christe; Michael Gerken; Ralf Haiges; Stefan Schneider; Thorsten Schroer; Irena Tsyba; Robert Bau

doi:10.1021/ic0259078

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The (SO₂)₂N₃^- Anion

Karl O. Christe Michael Gerken Ralf Haiges Stefan Schneider Thorsten Schroer Irena Tsyba Robert Bau

Year: 2002 Journal: Inorganic Chemistry Vol: 42 (2)Pages: 416-419 Publisher: American Chemical Society

DOI: 10.1021/ic0259078

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Abstract

The recently proposed (SO2)2N3- anion was structurally characterized by single-crystal X-ray diffraction of the [Cs][(SO2)2N3] salt (P2(1)/c, a = 8.945(2) A, b = 10.454(2) A, c = 8.152(2) A, beta = 109.166(3) degrees, Z = 4, and R1 = 0.0329 at 130 K). In the (SO2)2N3- anion, both SO2 ligands are coordinated to one terminal nitrogen atom of the N3- anion.

Keywords:

Chemistry Ion Crystallography X-ray crystallography Nitrogen atom Salt (chemistry) Crystal structure Atom (system on chip) Nitrogen Diffraction Inorganic chemistry Stereochemistry Group (periodic table) Physical chemistry Organic chemistry

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Crystal structures of chemical compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Crystallography and molecular interactions

Physical Sciences → Chemistry → Physical and Theoretical Chemistry

Radical Photochemical Reactions

Physical Sciences → Chemistry → Organic Chemistry

The (SO₂)₂N₃^- Anion

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