Indium-Catalyzed N-Formylation of Amines under Solvent-Free Conditions

Doo Ok Jang; Joong-Gon Kim

doi:10.1055/s-0029-1219784

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Indium-Catalyzed N-Formylation of Amines under Solvent-Free Conditions

Doo Ok Jang Joong-Gon Kim

Year: 2010 Journal: Synlett Vol: 2010 (08)Pages: 1231-1234 Publisher: Thieme Medical Publishers (Germany)

DOI: 10.1055/s-0029-1219784

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Abstract

We have developed a simple, mild method for N-formylation of a wide variety of amines in the presence of indium metal as a catalyst under solvent-free conditions. This reaction is applicable to the chemoselective N-formylation of amino groups and α-amino acid esters without epimerization.

Keywords:

Formylation Chemistry Catalysis Indium Epimer Organic chemistry Solvent Combinatorial chemistry

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Carbon dioxide utilization in catalysis

Physical Sciences → Chemical Engineering → Process Chemistry and Technology

Asymmetric Hydrogenation and Catalysis

Physical Sciences → Chemistry → Inorganic Chemistry

Hydrogen Storage and Materials

Physical Sciences → Materials Science → Materials Chemistry

Indium-Catalyzed N-Formylation of Amines under Solvent-Free Conditions

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