JOURNAL ARTICLE
Selective Oxidation of Propargylic Alcohols into α,β-Acetylenic Aldehydes with a TiCl4/Et3N System
Zhenfu HanHiroshi ShinokuboKoichiro Oshima
Year: 2001 Journal: Synlett Vol: 2001 (09)Pages: 1421-1422 Publisher: Thieme Medical Publishers (Germany)
Abstract
A TiCl4/Et3N combination proved to be effective for the selective oxidation of propargylic alcohols into α,β-acetylenic aldehydes in good yields. Treatment of 2-hexyne-1,6-diol with TiCl4/Et3N provided 6-hydroxy-2-hexynal in good yield.
Keywords:
Chemistry Yield (engineering) Organic chemistry Alcohol oxidation Diol Aldehyde Alcohol Combinatorial chemistry Catalysis
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Citation History
Topics
Synthetic Organic Chemistry Methods
Physical Sciences → Chemistry → Organic Chemistry
Catalytic Alkyne Reactions
Physical Sciences → Chemistry → Organic Chemistry
Oxidative Organic Chemistry Reactions
Physical Sciences → Chemistry → Organic Chemistry
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