JOURNAL ARTICLE
Refinement of CaBa2(HPO4)2(H2PO4)2
Lotfi Ben TaharL.S. SmiriAhmed Driss
Year: 1999 Journal: Acta Crystallographica Section C Crystal Structure Communications Vol: 55 (11)Pages: 1757-1759 Publisher: Wiley
Abstract
The structural model proposed previously for calcium dibarium bis(hydrogenphosphate) bis(dihydrogenphosphate) from X-ray powder data is confirmed by the present single-crystal study. The structure consists of infinite [Ca(HPO 4 ) 2 (H 2 PO 4 ) 2 ] anionic chains built up from CaO 6 , HPO 4 and H 2 PO 4 polyhedra linked via Ca-O-P bonds. These chains are held together by nine-coordinate Ba 2+ cations. A two-dimensional network of hydrogen bonds contributes to the linkage of these chains.
Keywords:
Materials science
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Citation History
Topics
Chemical Synthesis and Characterization
Physical Sciences → Environmental Science → Industrial and Manufacturing Engineering
X-ray Diffraction in Crystallography
Physical Sciences → Materials Science → Materials Chemistry
Crystal Structures and Properties
Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials
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