JOURNAL ARTICLE
ChemInform Abstract: Copper‐Catalyzed Enantioselective Propargylic Amination of Propargylic Esters with Amines: Copper—Allenylidene Complexes as Key Intermediates.
Gaku HattoriKen SakataHiroshi MatsuzawaYoshiaki TanabeYoshihiro MiyakeYoshiaki Nishibayashi
Year: 2010 Journal: ChemInform Vol: 42 (2) Publisher: Wiley
Abstract
Abstract Under optimized conditions, a wide variety of secondary amines undergo the title reaction with propargylic acetates with up to 98% enantioselectivity.
Keywords:
Chemistry Copper Enantioselective synthesis Amination Catalysis Organic chemistry Combinatorial chemistry
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Topics
Catalytic Alkyne Reactions
Physical Sciences → Chemistry → Organic Chemistry
Asymmetric Hydrogenation and Catalysis
Physical Sciences → Chemistry → Inorganic Chemistry
Asymmetric Synthesis and Catalysis
Physical Sciences → Chemistry → Organic Chemistry
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