JOURNAL ARTICLE
ChemInform Abstract: Synthesis and Characterisation of Tungsten and Rhenium Aluminopolyhydrides: X‐Ray Crystal Structures of (Me3P)3H3W(μ‐H)2Al(H)(μ‐OBu)2Al(H)(μ‐H)2WH3(PMe3)3 and (Me3P)3H3W(μ‐H)2Al(H)(μ‐H)2WH3(PMe3)3.
Andrew R. BarronD. LyonsG. WilkinsonMajid MotevalliAndrew HowesM.B. Hursthouse
Year: 1986 Journal: Chemischer Informationsdienst Vol: 17 (22) Publisher: Wiley
Abstract
Abstract The reaction of WCl 4 (PMe 3 ) 3 with LiAlH 4 in refluxing THF (48 h) leads to one of the title compounds, (Ia) (with bridging butoxide groups arising from the cleavage of THF by aluminium hydride), whereas in Et 2 O (20°C, 2h) the product (Ib) is formed.
Keywords:
Rhenium Tungsten Crystal structure Hydride Crystallography Chemistry Cleavage (geology) X-ray crystallography Inorganic chemistry Materials science Physics Diffraction Metal Organic chemistry
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Topics
Asymmetric Hydrogenation and Catalysis
Physical Sciences → Chemistry → Inorganic Chemistry
Organometallic Complex Synthesis and Catalysis
Physical Sciences → Chemistry → Organic Chemistry
Synthesis and characterization of novel inorganic/organometallic compounds
Physical Sciences → Chemistry → Inorganic Chemistry
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