JOURNAL ARTICLE
Carbonyl Allylation Catalyzed by Silica-Bound Poly-γ-Cyanopropylsiloxane Palladium Complex
Ming CaiCai Sheng SongXian Huang
Year: 1997 Journal: Synthetic Communications Vol: 27 (17)Pages: 3087-3093 Publisher: Taylor & Francis
Abstract
Abstract The silica - bound poly - γ - cyanopropylsiloxane palladium complex has been found to catalyze the allylation of carbonyl compounds via the formation of π - allylpalladium complexes, using allyl chloride or allyl acetate as allylating agent and SnCl2 as reducing agent. This polymeric palladium complex is stable and can be reused.
Keywords:
Chemistry Palladium Catalysis Polymer chemistry Allyl chloride Chloride Organic chemistry Silica gel
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5
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1.19
FWCI (Field Weighted Citation Impact)
7
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0.80
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Topics
Polyoxometalates: Synthesis and Applications
Physical Sciences → Materials Science → Materials Chemistry
Catalytic Cross-Coupling Reactions
Physical Sciences → Chemistry → Organic Chemistry
Organoboron and organosilicon chemistry
Physical Sciences → Chemistry → Organic Chemistry
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