Facile One-Pot Synthesis of 1-Alkyl-3-polyfluoroalkyl Imidazolium Ionic Liquids
Hoon KimHyun‐Joo LeeDong KimDebby NataliaDihn Quan NguyenDong Jin SuhHonggon Kim
Abstract
Imidazolium-based ionic liquids bearing a polyfluorinated alkyl group on the cation were efficiently synthesized in excellent yields and selectivities from the one-pot reaction of a fluoroolefin with [1-alkyl-3H-imidazolium]X, where X = Cl, NO3, CF3CO2, BF4 or (CF3SO2)2N, formed in situ from the interaction of an alkylimidazole with an acid, HX.
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