JOURNAL ARTICLE

ENHANCED PHTOCATALYTIC ACTIVITY OF α-FE2O3 NANOPARTICLES USING 2D MOS2 NANOSHEETS

M. BehtajParvaneh Sangpour

Year: 2018 Journal:   Advanced Ceramics Progress Vol: 3 (4)Pages: 34-40

Abstract

α‒Fe2O3/MoS2 nanocomposites were synthesized via hydrothermal method and characterized in terms of crystal structure, particle size and morphology, elemental purity and optical properties. Results confirmed the formation of α‒Fe2O3/MoS2 nanocomposites containing hematite nanoparticles with average diameter of 40 nm and MoS2 nanosheets with hexagonal crystal structure and sheet thickness of < 10 nm. Optical band gap measurements revealed decrease of the band gap of α‒Fe2O3 nanoparticles from 2.65 to 2.15 eV upon loading MoS2 nanosheets. The as‒synthesized α‒Fe2O3/MoS2 nanocomposites showed a high absorption capability in the visible irradiation. Photocatalytic examinations showed over 98 % degradation of Rhudamine Blue (Rh B) organic dye within 75 min. α‒Fe2O3/MoS2 nanocomposites enhanced the rate of degradation as compared to pure α‒Fe2O3 nanoparticles and MoS2 nanosheets.

Keywords:
Nanocomposite Materials science Nanoparticle Hydrothermal circulation Hematite Band gap Photocatalysis Chemical engineering Crystal structure Degradation (telecommunications) Hydrothermal synthesis Absorption (acoustics) Visible spectrum Crystal (programming language) Particle size Nanotechnology Morphology (biology) Composite material Crystallography Chemistry Metallurgy Optoelectronics Catalysis Organic chemistry

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