Enhanced Photocatalytic Performance of TiO2 by β-Cyclodextrin for the Degradation of Organic Dyes

Abstract

In this work, an efficient photocatalyst based on β-cyclodextrin-glycine-modified TiO2 nanoparticles (TiO2-Gly-βCD NPs) was successfully synthesized. The photocatalytic activity of the prepared TiO2-Gly-βCD was tested on the degradation of methylene blue (MB) and methyl orange (MO) dyes. The enhanced surface properties of TiO2-Gly-βCD photocatalyst generated excellent photocatalytic performance for the photocatalytic degradation of dyes in aqueous solution. These were strongly attributed to the presence of the functional hydroxyl groups and the inner cores of the hydrophobic cavity in β-CD to form inclusion complexes with organic molecules. As compared to the pure TiO2 and TiO2 modified by Gly, the dye degradation rate under UV irradiation was considerably enhanced by TiO2/Gly/βCD as a photocatalyst. In addition, the sonocatalytic degradation of dyes was investigated, and it was found that the ultrasonic waves slightly enhanced the degradation time of dyes. The results indicated that the first-order kinetic model well describes the degradation of MB and MO dyes by TiO2-Gly-βCD. Furthermore, the chemical oxygen demand (COD) values were determined for real industrial wastewater and treated wastewater.