Rhodium(<scp>iii</scp>)-catalysed decarbonylative annulation through C–H activation: expedient access to aminoisocoumarins by weak coordination

Sivakalai Mayakrishnan; Yuvaraj Arun; Narayanan Uma Maheswari; Paramasivan T. Perumal

doi:10.1039/c8cc07167e

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Rhodium(iii)-catalysed decarbonylative annulation through C–H activation: expedient access to aminoisocoumarins by weak coordination

Sivakalai Mayakrishnan Yuvaraj Arun Narayanan Uma Maheswari Paramasivan T. Perumal

Year: 2018 Journal: Chemical Communications Vol: 54 (84)Pages: 11889-11892 Publisher: Royal Society of Chemistry

DOI: 10.1039/c8cc07167e

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Abstract

Rh-Catalysed decarbonylative annulation of isatoic anhydrides with alkynes through C–H activation for the direct synthesis of 8-aminoisocoumarins has been developed.

Keywords:

Annulation Rhodium Chemistry Catalysis Stereochemistry Medicinal chemistry Combinatorial chemistry Organic chemistry

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Catalytic C–H Functionalization Methods

Physical Sciences → Chemistry → Organic Chemistry

Catalytic Cross-Coupling Reactions

Physical Sciences → Chemistry → Organic Chemistry

Catalytic Alkyne Reactions

Physical Sciences → Chemistry → Organic Chemistry

Rhodium(iii)-catalysed decarbonylative annulation through C–H activation: expedient access to aminoisocoumarins by weak coordination

Abstract

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